| David Ferrer (SPA-1) | Xavier Malisse (BEL) | |
| Edouard Roger-Vasselin (FRA) | Yen-Hsun Lu (TAI) | |
| Roberto Bautista (SPA) | Stéphane Bohli (ZWI-Kwal) | 3-6, 7-6 (7/5), 7-6 (14/12) |
| Carlos Berlocq (ARG) | Marcos Baghdatis (CYP-6) | 6-2, 6-4 |
| Evgeny Donskoy (RUS) | John Isner (VS-3) | 6-7 (3/7), 6-3, 6-4 |
| Robin Haase (NED) | Leonardo Mayer (ARG) | 4-6, 6-1, 6-4 |
| Nicolas Mahut (FRA-Kwal) | Ricardas Berankis (LIT) | |
| Andrey Kuznetsov (RUS) | Daniel Gimeno (SPA-8) | 7-6 (7/4), 6-3 |
| Guillermo García-López (SPA) | Victor Hanescu (ROE-7) | 6-4, 6-3 |
| Daniel Brands (DUI) | Jesse Huta Galung (NED-WC) | 6-3, 6-2 |
| Jan Hernych (TSJ-Kwal) | David Goffin (BEL) | |
| Michaël Llodra (FRA) | Benoît Paire (FRA-4) | |
| Jérémy Chardy (FRA-5) | Lucas Pouille (FRA-Kwal) | |
| Rogério Dutra Silva (BRA) | Marius Copil (ROE-WC) | |
| Paolo Lorenzi (ITA) | Thiemo de Bakker (NED-WC) | 7-6 (7/2), 7-6 (7/4) |
| Igor Sijsling (NED) | Stanislas Wawrinka (ZWI-2) |
| Milos Raonic (CAN-1WC) | (Bye) | |
| Denis Istomin (OEZ) | Ivan Dodig (KRO) | |
| Viktor Troicki (SER) | Martin Klizan (SLW) | |
| Fabio Fognini (ITA-8) | Grega Zemlja (SLO) | 6-7 (6/8), 6-2, 6-4 |
| Juan Monaco (ARG-4) | (Bye) | |
| Jarkko Nieminen (FIN) | Feliciano Lopez (SPA) | |
| Albert Ramos (SPA) | James Blake (VS-Kwal) | 6-2, 6-4 |
| Fernando Verdasco (SPA) | Alexandr Dolgopolov (OEK-6) | 1-6, 6-3, 6-2 |
| Andreas Seppi (ITA-7) | Guillaume Rufin (FRA-Kwal) | 3-6, 6-3, 6-4 |
| Ryan Harrison (VS-Kwal) | Paul-Henri Mathieu (FRA) | 6-4, 2-6, 7-6 (7/4) |
| Radek Stepanek (TSJ) | Marinko Matosevic (AUS) | |
| Philipp Kohlschreiber (DUI-3) | (Bye) | |
| Kevin Anderson (ZAF-5) | Julien Benneteau (FRA) | |
| Bernard Tomic (AUS) | James Ward (GBR-WC) | |
| Kyle Edmund (GBR-WC) | Kenny De Schepper (FRA-Kwal) | 6-4, 6-4 |
| Gilles Simon (FRA-2) | (Bye) |
| Roberta Vinci (ITA-1) | Kaia Kanepi (EST) | |
| Simona Halep (ROE) | Annika Beck (DUI) | 6-1, 2-6, 6-3 |
| Stefanie Vögele (ZWI) | Joelia Poetintseva (KAZ-Kwal) | 7-5, 4-6, 7-5 |
| Daniela Hantuchova (SLW-WC) | Lesia Tsurenko (OEK-LL) | |
| Carla Suarez (SPA-3) | Johanna Larsson (ZWE) | 6-3, 6-2 |
| Sofia Arvidsson (ZWE) | Ayumi Morita (JAP) | 3-6, 6-2, 6-4 |
| Irina Begu (ROE) | An-Sophie Mestach (BEL-Kwal) | 6-7 (6/8), 6-3, 6-4 |
| Tsvetana Pironkova (BUL) | Kristina Mladenovic (FRA-8) | 6-4, 6-4 |
| Urszula Radwanska (POL-7) | Olga Govortsova (WRU) | 6-2, 6-0 |
| Magdalena Rybarikova (SLW) | Arantxa Rus (NED-WC) | 7-5, 6-2 |
| Michaëlla Krajicek (NED-WC) | Silvia Soler (SPA) | 7-5, 6-4 |
| Francesca Schiavone (ITA) | Kirsten Flipkens (BEL-4) | |
| Garbiñe Muguruza (SPA-Kwal) | Mona Barthel (DUI-5) | 7-5, 1-6, 6-2 |
| Lauren Davis (VS) | Andrea Hlavackova (TSJ-Kwal) | 6-3, 6-4 |
| Anabel Medina G. (SPA) | Kiki Bertens (NED) | 6-1, 6-2 |
| Dominika Cibulkova (SLW-2) | Lourdes Domínguez (SPA) | 6-1, 6-7 (5/7), 7-6 (7/3) |
| Agnieszka Radwanska (POL-1) | Jamie Hampton (VS-Kwal) | |
| Johanna Konta (GBR-WC) | Su-wei Hsieh (TAI) | |
| Klara Zakopalova (TSJ) | Lucie Safarova (TSJ) | |
| Samantha Stosur (AUS-WC) | Nadja Petrova (RUS-8) | |
| Angelique Kerber (DUI-3) | Sorana Cirstea (ROE) | |
| Olga Puchkova (RUS-Kwal) | Jekaterina Makarova (RUS) | |
| Yuliya Beygelzimer (OEK-Kwal) | Laura Robson (GBR) | |
| Tamira Paszek (OOS) | Caroline Wozniacki (DEN-5) | |
| Maria Kirilenko (RUS-6) | Bojana Jovanovski (SER) | 7-6 (7/5), 6-1 |
| Elena Baltacha (GBR-WC) | Kristýna Plíšková (TSJ-Kwal) | |
| Yanina Wickmayer (BEL) | Christina McHale (VS) | 6-3, 6-4 |
| Monica Niculescu (ROE) | Petra Kvitova (TSJ-4) | |
| Jelena Vesnina (RUS) | Ana Ivanovic (SER-7) | 2-6, 6-4, 6-3 |
| Heather Watson (GBR) | Varvara Lepchenko (VS) | 6-3, 6-4 |
| Marion Bartoli (FRA) | Flavia Pennetta (ITA) | 6-3, 6-2 |
| Alizé Cornet (FRA) | Li Na (CHN-2WC) |
